englelab / Molecular Complexity through

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Title	Molecular Complexity through
Description	Molecular Complexity through Catalysis Menu Home Research Publications Outreach The Team Keary Current Members GROUP ALUMNI Resources ORGANOMETALLICS (CHE
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englelab.com Valuation

US$3,083,283

Last updated: 2023-05-18 16:29:50

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Molecular Complexity through Catalysis Menu Home Research Publications Outreach The Team Keary Current Members GROUP ALUMNI Resources ORGANOMETALLICS (CHEM 530) 2023 ORGANOMETALLICS (CHEM 530) 2021 ORGANOMETALLICS (CHEM 530) 2019 Team Challenges Problem Sets Literature Reviews Safety Minute Contact Latest Pre-Print Describes a Unique Sigma-Bond Annulation Process May 11, 2023 The newest method to emerge from the group builds on our interest in developing catalytic strong activation reactions via β-X elimination. We have previously demonstrated that Pd II (π-olefin) intermediates generated in this manner can be engaged in nucleopalladation / protodepalladation sequences to effect functional group metathesis of an outgoing C(sp 3 )–X (X = C, N, O, F, etc.) for a new C(sp 3 )–C or C(sp 3 )–N. In our newest pre-print, Hui-Qi, Jing-Chen, and collaborators from Pfizer extend the reach of this approach, demonstrating annulation of transiently generated Pd II (π-olefin) intermediates via β-X

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